How much ammonia will be released from neutralizing 1ppm total chlorine?

Miami Reef

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I filled a 5 gallon bucket with tap water.

Hach test kit: 0ppm free chlorine; 1ppm total chlorine

How much ammonia will become released from neutralizing the 1ppm chloramine with sodium thiosulfate?

@Randy Holmes-Farley
 

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I filled a 5 gallon bucket with tap water.

Hach test kit: 0ppm free chlorine; 1ppm total chlorine

How much ammonia will become released from neutralizing the 1ppm chloramine with sodium thiosulfate?

@Randy Holmes-Farley
Your question is unclear - I know you asked Randy - but maybe you want to re-phrase. Why do you think that the 1 ppm chlorine represents 1 ppm chloramine? Here is a link that might help your question: https://www.koiphen.com/forums/show...ia-is-released-when-adding-sodium-thiosulfate
 
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MnFish1

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Total chlorine - free chlorine = chloramine
Based on what? There can be many compounds binding with chlorine. Note - I'm not disagreeing with you. I'm just trying to tease out what your asking
 
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The total residual Chlorine is nothing more than the sum of the combined Chlorine(chloramines) and the free residual Chlorine.


Chloramines are a type of combined chlorine that form in water and then off gas into the air above the water.

The sum of combined chlorine and free chlorine is total chlorine (combined chlorine + free chlorine = total chlorine).
 

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The answer depends on the unit of measure used for the chloramine, but 1 ppm of actual chloramine will release 0.33 ppm of ammonia.

The Hach chlorine tests say "Cl2."

I'm skeptical when (other) people claim to detect >2 ppm ammonia in their tap water given that the regulatory limit for Cl2 is 4 mg/L and chloramine is made by dosing chlorine and ammonia in a ~4.5-5:1 ratio...
 

Randy Holmes-Farley

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Can you elaborate on this? I’m not sure I’m understanding that part.

If a kit measures total chlorine or measures chloramine as chlorine (cl2), then 1 ppm real chloramine (NH2Cl) will read as about 1.4 ppm chlorine (cl2) because chloramine weighs less than cl2.

Its even more complicated than that because chloramine can also include other species such as NHCl2 and NCl3.
 

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