Post your DIY additives here!

Randy Holmes-Farley

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FWIW, this is from wikipedia:


"Borax, also known as sodium borate, sodium tetraborate, or disodium tetraborate"

and they have a picture that shows how the tetra (4 ) borate part works:

1583002031987.png
 

Rick Strauss

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I’ve been looking. Anybody have a recipe for potassium chloride to up my potassium?
 

Randy Holmes-Farley

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Use this calculator, pick the entry for potassium from potassium nitrate, and use 74% of the dosed amount (so 74 mL if it says 100 mL).

 

AlbertGF

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Hi,

After reading this thread I tried to do a list with all additives that I found in Triton and Aquaforest and to write the chemical formula beside.

Can anyone check if the formulas I wrote are correct?. I mean that I want to be sure that I am not writing down some molecules that are incompatible with reef life.

I am not asking for quantities or grams or moles or nothing like that, neither asking if I should add those additives to the tank. I'm only asking if those molecules are good as reef tank additives or not. After that I will calculate weights, moles and doses.

Another question I have is that I found that some elements can appear in many different molecules, how can I know which should I use? For example Lithium, it appears in Li2SO4, LiCl and LiCO3. How can I know which of these is best as additive? Do I have to look for the solubility? Or is there any form of these that is more toxic than the others? Or simply I have to look for the availability and price?

Thank you so much!

AquaforestTriton
BariumBaSBaCl2*2(H2O)BaCO3
BoronBoronH3BO3
BromineBromineKBr
CalciumCalcium
ChromiumChromiumCrCl3*6(H2O)
CobaltCobaltCoCl2*6(H2O)
FluorineFluorineNaF
IodineIodineKI
IronIronFeSO4*7(H2O)
KH
LithiumLithiumLi2SO4LiClLi2CO3
MagnesiumMagnesiumMgSO4*7(H2O)MgCl2*6(H2O)
ManganeseManganeseMnSO4*1(H2O)
MolybdenumMolybdenumNa2MoO4
NickelNickelNiSO4*6(H2O)NiCl2
PotassiumPotassiumKCl
RubidiumRbCl
StrontiumStrontiumSrCl2*6(H2O)
Sulphur
VanadiumVanadiumNaVO3
ZincZincZnSO4*7(H2O)ZnCl2
 

Randy Holmes-Farley

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Another question I have is that I found that some elements can appear in many different molecules, how can I know which should I use? For example Lithium, it appears in Li2SO4, LiCl and LiCO3. How can I know which of these is best as additive? Do I have to look for the solubility? Or is there any form of these that is more toxic than the others? Or simply I have to look for the availability and price?

For anyone interested in dosing DIY chemicals, the critical first step is to determine what form any particular element takes in seawater. That information is available in many places, such as the book "Chemical Oceanography" by Millero.

Some elements take many forms, so then one needs to dig even deeper and understand which forms are most useful to organisms and which ones might be toxic. Iodine is a good example, which is naturally present as iodide (I-), iodate, IO3-, and a large number of lower concentration organic and inorganic forms. Iodide, while not the highest concentration form (iodate is), is more bioavailable and the one that I recommend dosing (if one chooses to dose iodine, whether it is useful or not is a different question).
 

N.Sreefer

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For anyone interested in dosing DIY chemicals, the critical first step is to determine what form any particular element takes in seawater. That information is available in many places, such as the book "Chemical Oceanography" by Millero.

Some elements take many forms, so then one needs to dig even deeper and understand which forms are most useful to organisms and which ones might be toxic. Iodine is a good example, which is naturally present as iodide (I-), iodate, IO3-, and a large number of lower concentration organic and inorganic forms. Iodide, while not the highest concentration form (iodate is), is more bioavailable and the one that I recommend dosing (if one chooses to dose iodine, whether it is useful or not is a different question).
Would bulk rock phosphate for organic farming work as an additive? Jw out of curiosity. Another thing I was wondering about is greensand. Mainly because I already buy literal tons of both.
 

Randy Holmes-Farley

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Would bulk rock phosphate for organic farming work as an additive? Jw out of curiosity. Another thing I was wondering about is greensand. Mainly because I already buy literal tons of both.

Additive for what purpose?

Do you have a link to the product you are referring to? Lots of different things might be called "bulk rock phosphate".
 

N.Sreefer

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Additive for what purpose?

Do you have a link to the product you are referring to? Lots of different things might be called "bulk rock phosphate".
Phosphorite I have no idea how soluble it would be but I was thinking its a slow release source of phosphate for supplementing a LNS and would probably be colonized by beneficial bacteria. And jersey greensand for potassium. I've only ever used these in horticulture so I have no idea if they would be of use (sorry if its a dumb question!). But the price is right.
 

N.Sreefer

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Phosphorite I have no idea how soluble it would be but I was thinking its a slow release source of phosphate for supplementing a LNS and would probably be colonized by beneficial bacteria. And jersey greensand for potassium. I've only ever used these in horticulture so I have no idea if they would be of use (sorry if its a dumb question!). But the price is right.
By greensand I'm referring to glauconite greensand
 

Randy Holmes-Farley

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Phosphorite I have no idea how soluble it would be but I was thinking its a slow release source of phosphate for supplementing a LNS and would probably be colonized by beneficial bacteria. And jersey greensand for potassium. I've only ever used these in horticulture so I have no idea if they would be of use (sorry if its a dumb question!). But the price is right.

Both potassium and phosphate additives are cheap as food grade products (sodium phosphate, potassium chloride). I don't think trying to get a rock to slowly dissolve is the easiest or best way to dose these.
 

zachtos

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Hello, I made a spread sheet that has calculations on how to make all the elements you need. I've been running over 2 years now no water change. Feel free to use this to make a better calculator or whatever you wish as a community. Let me know if anyone finds a mistake, but it's obviously working.
zachtos diy ICP supplements

1616432866909.png
 

AlbertGF

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For anyone interested in dosing DIY chemicals, the critical first step is to determine what form any particular element takes in seawater. That information is available in many places, such as the book "Chemical Oceanography" by Millero.

Some elements take many forms, so then one needs to dig even deeper and understand which forms are most useful to organisms and which ones might be toxic. Iodine is a good example, which is naturally present as iodide (I-), iodate, IO3-, and a large number of lower concentration organic and inorganic forms. Iodide, while not the highest concentration form (iodate is), is more bioavailable and the one that I recommend dosing (if one chooses to dose iodine, whether it is useful or not is a different question).
Well , thank you, but I was only trying to reproduce some of the Aquaforest additives for myself and was looking for some help deciding what chemical was a better choose for each additive. I have read many forums and threads but I am not chemist nor oceanographer, my only capability is to calculate how much of each product I should add to an aquarium based on the ICP results. The problem is that I do not know if the chemicals listed above are good enough or there are better options.
 

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Hello, I made a spread sheet that has calculations on how to make all the elements you need. I've been running over 2 years now no water change. Feel free to use this to make a better calculator or whatever you wish as a community. Let me know if anyone finds a mistake, but it's obviously working.
zachtos diy ICP supplements

1616432866909.png
Looks like I picked a wonderful day to discover and follow this thread!
 

AlbertGF

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Hello, I made a spread sheet that has calculations on how to make all the elements you need. I've been running over 2 years now no water change. Feel free to use this to make a better calculator or whatever you wish as a community. Let me know if anyone finds a mistake, but it's obviously working.
zachtos diy ICP supplements

1616432866909.png
Wow! Thank you for sharing this. I will study your spread sheet!
 

zachtos

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Wow! Thank you for sharing this. I will study your spread sheet!
I'm an Electrical Engineer, not a chemist, but I understand molecular formulas etc. I do NOT know if the chloride based versions of elements I chose are bio-available or not. I'm not even sure Randy can answer that for each item. And several elements, may appear to be used by my corals (barium for instance), but I dose them anyways. They may precipitate out, or be used as a by product (like magnesium). I only know what has worked for me is to stop doing water changes and just re-up elements that are missing. I don't get hung up on the amounts anymore, as long as they are not zero, then they are not a bottleneck. I would like more lighting though.
 
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