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Because 10% took your nitrate down to 22. The first 10% was done before the test that read 25. Then you tested again and did another so your nitrates are around 23ppm. To make a sizable dip in nitrates you must do 50%+. 50% will get nitrates to 12. 75% will be around 8ppm. You subtract the same % from the total nitrates based on % of water change
My total system is 65 gallon. Maybe the rocks and substrate is equal to 5 gallon worth of water, let's call it 55 gallons total water only in the system. 10 gallons WC is 18% of total water system. So far I did 36% of WC. You are saying if I did 14% WC more (which bring it to total of 50% WC), it should bring my nitrates down to 12?
Is there a reference that I can read about relation between WC % and Nitrate amount?