What are you putting in your ATO?? My ATO runs off a 35g plastic trash bin and looks perfectly fine with just RODI in it even after a year. Maybe you need a cover for it to keep the dust and stuff out??Just had a thought, could the stagnant water of my atom be causing this issue? I have it in an open tub next to my sump so, I top it up roughly once a week and it just sits there until it's used, I was just looking at it and it looks sort of similar to when you leave a glass lying around anit gammy and white...
Aside from that, it's highly unlikely it has any negative effect on the corals. I have heard that containers of aminos and other things which can grow a variety of bacteria will just be more 'food' for the corals.