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The answer to that question can be very complex. However, in general without some means of export, sequestration or conversion, all of that stuff can become problematic in the tank.now that I'm learning more about reefing and how a skimmer works, I'm wondering how do tanks actually go more mature and survive without a skimmer.? I mean, my skimmer is taking out all this yellow gunk from my tank on a daily basis. If didn't have that skimmer like a lot of people don't have skimmers then what happens to all that yellow gunk? would not having a protein skimmer just make me more of a slave to water changes? Even then, if I took out a 10% water change, I'm still leaving 90% of that gunk in my tank.
It is hard to get a handle on what the balance needs to be when you are new and without context or experience. The skimmer provides a time tested and proven method of export and will get you through the next year or so as you wrap your head around how everything fits and works together with chemistry and biology. You may one day decide to go without the skimmer or water changes, etc.
In your case the skimmer and mechanical filter (roller mat) are both exporting compounds that will build up in your system. You could arguably do without one or the other, but as a new aquarist I would NOT go without the skimmer. You may or may not want to experiment with bypassing the roller filter at some point but leave it online for now.