I understand the concept of what's being implied by the way in which the light is used and converterted.Can't change the laws of physics, if you absorp the photon like you say you absorp the energy. Any and all of that energy that is not used has to go somewhere. The simplest way to get rid of it is releasing it as heat. Since corals are very sensitive to heat, that isn't the best solution. The mechanism they therefore use is converting it back in a photon and releasing it. Now the question is, is increasing this fluorescence by adding more blue spectrum really helping the coral?
Like Lasse said the actual photo reactive center found in chlorophyll contains a primairy pigment p680 or p700 (p=pigment and the 680 and 700 stand for the nm of light of the photon that is directly converted in an electron by this pigment, so red light). That electron is what is passed on for the chemical reaction. Directly attached to this photo reactive center is a secondairy pigment that absorps light in the 400nm to 500nm range (so blue light) to create an electron that is passed on, so transported to the primairy pigment. Like any and all kind of transport there is some kind of loss/inefficiency. All other pigments found in corals that use light at different wavelentgths are attached to this photo reactive system and therefore the electrons created also need to be transported along a longer pathway probably incuring greater losses than even that of the blue absorption pigment.
Red light of the right wavelength is therefore most efficient and in theory all corals need if you provide the right amount, it would make them really ugly. All flesh would be transparent so you would see nothing but white skeleton except for a minimum amount of brown zoõxanthellae. Don't think they would be very healthy though under such unnatural conditions. The major problem with red spectrum light is that there really isn't any much room for fluorescence if you get to much of it, so the only option left may be trying to survive the heatstress. Which corals are bad at.
Going off your last paragraph, we are talking about coral health and providing them with the optimum conditions for colouration and growth. You've said there that red would likely result in ugly corals, and also cause them to die of heat stress?
This is a study of stylophora pistillata under a number of different lighting scenarios at 2 intensities. You can see that by week 6 that only 3 groups have zero mortality. Those are either all blue or blue/red with low intensity. I fully understand your point that it maybe needs to be regulated so accurately to provide the absolute correct amount, but with regards to what we do in this hobby it clearly serves no benefit. There is a reason the blue light is so successful, and I may be misunderstanding the direct link to energy and it's usefulness in photosynthesis. But if we revisit my original point of all par isn't equal, the arguement that certain spectrums are more important than others (whether it be red or blue) then I think both perspectives back this