RODI expired, TDS= 2...whats up?

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
72,100
Reaction score
69,741
Location
Massachusetts, United States
Rating - 0%
0   0   0
Well it's a new unit, so I have no clue. It's designed to read zero, but I agree that while the first DI may have been bad, I have no reason to believe that she second is.

I read online that if the electrodes in a flow through TDS meter are not installed properly, the meter will always read 2 or 3. Apparently they are very orientation specific. I did not install the TDS electrodes, so I'm wondering if that's what's happening here.

In the meantime, if this is true, that means I may very well have an essentially unused di cartridge that is now wet. Any way to keep it and use it when the newly acquired one goes bad?

I don’t understand how orientation causes an issue, but they are very cheaply made for ro/di applications and certainly may have issues.
 

twentyleagues

2500 Club Member
View Badges
Joined
Mar 27, 2023
Messages
3,408
Reaction score
3,630
Location
Flint
Rating - 0%
0   0   0
I don’t understand how orientation causes an issue, but they are very cheaply made for ro/di applications and certainly may have issues.
I have wondered that myself. I was told the water needs to be flowing in between the electrodes. I would think that would still happen in either orientation. But not a scientist so I just do what I am told.
 

Buckeye Hydro

Valuable Member
View Badges
Joined
Dec 17, 2013
Messages
1,524
Reaction score
1,036
Location
Ohio
Rating - 0%
0   0   0
I will pop the line out of the fitting and have a look.
Suggest you do not pop the probe out of the fitting. Once you scratch the probe it may not seal. Simply rotate the probe in the fitting until the notch is oriented as shown above.
 
Last edited:

Buckeye Hydro

Valuable Member
View Badges
Joined
Dec 17, 2013
Messages
1,524
Reaction score
1,036
Location
Ohio
Rating - 0%
0   0   0
The units are calibrated with the probes aligned perpendicular to the water flow. I've seen many times a difference of several ppm based upon the orientation of the probes.
 
Last edited:

Bosreef

Active Member
View Badges
Joined
Apr 30, 2020
Messages
314
Reaction score
339
Rating - 0%
0   0   0
Have nothing to add but wanted to shout out boston reefers! Fellow member here!
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
72,100
Reaction score
69,741
Location
Massachusetts, United States
Rating - 0%
0   0   0
The units are calibrated with the probes aligned perpendicular to the water flow. I've seen many time a difference of several ppm based upon the orientation of the probes.

Still makes no sense to me unless flow is so fast that there are air gaps in between.
 

Marcus H.

Community Member
View Badges
Joined
Sep 4, 2024
Messages
29
Reaction score
42
Location
Texas
Rating - 0%
0   0   0
Chris

Do you know what actual ions are contributing to your TDS? The 95 to 99% efficiency is just a rule of thumb. My water is high in Sodium and Bicarbonate. RO membranes typically only remove 95 to 96% of bicarbonate and for sodium it can be an even wider band. So in my system I see a 94% reduction coming out of the Ro Unit which is right inline with what I can expect. So I just roll with it The bicarbonate concentration of seawater is around 140 ppm and sodium is orders of magnitude more so in my case who cares.

If you are dealing with phosphates, nitrates, sulfates or some other ion then maybe it is worth it to chase it down.
 
OP
OP
C

Chrisv.

2500 Club Member
View Badges
Joined
Mar 17, 2012
Messages
3,379
Reaction score
3,998
Location
United States
Rating - 0%
0   0   0
Chris

Do you know what actual ions are contributing to your TDS? The 95 to 99% efficiency is just a rule of thumb. My water is high in Sodium and Bicarbonate. RO membranes typically only remove 95 to 96% of bicarbonate and for sodium it can be an even wider band. So in my system I see a 94% reduction coming out of the Ro Unit which is right inline with what I can expect. So I just roll with it The bicarbonate concentration of seawater is around 140 ppm and sodium is orders of magnitude more so in my case who cares.

If you are dealing with phosphates, nitrates, sulfates or some other ion then maybe it is worth it to chase it down.
I don't. I suppose icp mass spec could be used on the purified water to find out, but I honestly wonder if this isn't just a false positive. I have another (handheld) TDS meter that gives a TDS of zero and this in line TDS meter has given me the 2-3 ppm with old resin and with brand new resin.

Unfortunately I sort of cheaped out on the handheld TDS meter when I bought it many years ago, so it likely isn't very high quality. Then again if you look on Amazon it looks like a they all come from the same factory.
 

Marcus H.

Community Member
View Badges
Joined
Sep 4, 2024
Messages
29
Reaction score
42
Location
Texas
Rating - 0%
0   0   0
I don't. I suppose icp mass spec could be used on the purified water to find out, but I honestly wonder if this isn't just a false positive. I have another (handheld) TDS meter that gives a TDS of zero and this in line TDS meter has given me the 2-3 ppm with old resin and with brand new resin.

Unfortunately I sort of cheaped out on the handheld TDS meter when I bought it many years ago, so it likely isn't very high quality. Then again if you look on Amazon it looks like a they all come from the same factory.
You can send your water in to have it tested. I send mine to Texas A and M Agrilife extension office. The Soil, water, Forage testing Laboratory. I used an irrigation analysis but they have one for aquaculture. I would call and ask. They use both mass spectroscopy and simple titrations. You can also ship it there. It might be a good way to to determine how much time and money you want to throw at this. You could even send the post RO sample. I hope this is helpful.

 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
72,100
Reaction score
69,741
Location
Massachusetts, United States
Rating - 0%
0   0   0
You can send your water in to have it tested. I send mine to Texas A and M Agrilife extension office. The Soil, water, Forage testing Laboratory. I used an irrigation analysis but they have one for aquaculture. I would call and ask. They use both mass spectroscopy and simple titrations. You can also ship it there. It might be a good way to to determine how much time and money you want to throw at this. You could even send the post RO sample. I hope this is helpful.


For a tank sample, I’d be wary of using a method not designed for seawater. :)
 

Marcus H.

Community Member
View Badges
Joined
Sep 4, 2024
Messages
29
Reaction score
42
Location
Texas
Rating - 0%
0   0   0
Ahh yeah this is just for the RoDI or what is coming out of the tap! if I took seawater in there I would get a funny look for sure!
 

Righteous

Well-Known Member
View Badges
Joined
Jun 12, 2015
Messages
851
Reaction score
1,092
Location
Austin, TX
Rating - 0%
0   0   0
Do you have a photo of the inline meter and where it’s installed? Maybe it’s not installed after the resin but after the RO? Or is it possible you have more than one TDS meter attached? I have a BRS with 3 seperate inline meters with a readout with a switch.

IMG_0116.jpeg
 
OP
OP
C

Chrisv.

2500 Club Member
View Badges
Joined
Mar 17, 2012
Messages
3,379
Reaction score
3,998
Location
United States
Rating - 0%
0   0   0
Do you have a photo of the inline meter and where it’s installed? Maybe it’s not installed after the resin but after the RO? Or is it possible you have more than one TDS meter attached? I have a BRS with 3 seperate inline meters with a readout with a switch.

IMG_0116.jpeg
I’ll post a photo tomorrow— unfortunately mine is just the two way unit. I suspect I will need to replace it and when I do I’ll buy the three way.
 

Buckeye Hydro

Valuable Member
View Badges
Joined
Dec 17, 2013
Messages
1,524
Reaction score
1,036
Location
Ohio
Rating - 0%
0   0   0
I’ll post a photo tomorrow— unfortunately mine is just the two way unit. I suspect I will need to replace it and when I do I’ll buy the three way.
Or just add a single probe meter to supplement what you have
 

Buckeye Hydro

Valuable Member
View Badges
Joined
Dec 17, 2013
Messages
1,524
Reaction score
1,036
Location
Ohio
Rating - 0%
0   0   0
Air was my issue. I now just force production rate to slow with a ball valve to ensure DI cans stay completely full of water and no air.
Hmmm. If I understand correctly what you're doing will apply backpressure on the membrane - not a good thing. How about you just burp your DI housing(s) and don't allow the DI water to siphon out when you're done with production?
 
OP
OP
C

Chrisv.

2500 Club Member
View Badges
Joined
Mar 17, 2012
Messages
3,379
Reaction score
3,998
Location
United States
Rating - 0%
0   0   0
If anyone is interested in how this story ended, I bought a second of the same hm TDS meters and installed it. With both meters in line I was getting 0 TDS with the new one and 4-5 with the old one. Given that I already replaced the di resin and that it agrees with the results of the handheld meter, I'm calling it zero.
 

Cichlid Dad

2500 Club Member
View Badges
Joined
Jul 20, 2022
Messages
4,203
Reaction score
13,746
Location
Auburn
Rating - 0%
0   0   0
Air was my issue. I now just force production rate to slow with a ball valve to ensure DI cans stay completely full of water and no air.
If you are taking about the air left in the canister as you are looking at it, first it's fine, the resin in the tube is full of water, second , just turn on the unit and loosen the canister, the air will leak out, then tighten it once the air is gone.
 

TOP 10 Trending Threads

Back
Top