PSA: Do not use hydrogen peroxide to fight algae if you have shrimp

formallydehyde

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Too long; didn't read: I lost both a peppermint shrimp and a fire shrimp after using hydrogen peroxide spot treatment to get rid of a bad dinoflagellate outbreak in separate incidents. Both died during the night after treatment. Others have reported similar incidents. Don't use hydrogen peroxide treatment in a tank that has shrimp.

More detailed version:
I had two peppermint shrimp and one fire shrimp in a 20 gallon tank that ended up with a bad dinoflagellate outbreak. Part of the reason that I decided to treat the outbreak with peroxide was ironically that my fire shrimp *hated* stepping on the dinoflagellate mats. Every source I initially read said it was safe for invertebrates.

The first time I peroxide treated, I lost a peppermint shrimp but did not connect the peroxide to her death because the other peppermint shrimp survived, as well as my fire shrimp. So I thought it was a coincidence, and that the treatment was safe. I treated a second time without incident, though the two remaining shrimp looked a little irritated but nothing major.

The third time I peroxide treated, my fire shrimp started acting weird soon after, and she died that night. I performed some huge water changes after she started acting strange but it was already too late. Then I started looking deeper on here to see if there was a connection, and sure enough, other people had reported deaths of Lysmata genus shrimp after peroxide treatment. Unfortunately, this info was buried replies to larger threads about algae treatment, so I did not see them in time. If I had, I would have never used this method at all. From what I remember that others have said, it seems like death can happen even from small spot treatments in larger tanks or low doses in the water itself. So I don't think there's any shrimp-safe way to do it.

All my shrimp were named and I loved them a lot, my fire shrimp Socks in particular, was the star of my tank and I looked forward to seeing her excitedly pop out to beg for food when I got home from work. Her dying from my stupid decisions was really hard and it consequently took me a while after this happened to write this post.

My suspicion is shrimp are more susceptible to death from peroxide than other crustaceans because of how much more frequently they molt, and maybe their relative sensitivity to it depends on where they're at in their molt cycle. Some parts of Socks' remains looked like partially formed exoskeleton and both shrimp deaths happened late during the night, which is the time they always molted. Both were alive and active before then, so my educated guess is for some reason peroxide can trigger a premature, partial molt, which results in death. Shrimp also deal with exoskeletal infections by molting much more frequently, though these are usually complete molts, for what that's worth. The only surviving shrimp from this ordeal was the runtier peppermint shrimp, Junior, who molted far more infrequently than the other two shrimp. Junior is still alive today, actually. But again, this is all speculation.

I am also not 100% certain whether or not the lethality was from the peroxide *itself*, or possibly some kind of toxin released from a large number of dinoflagellates dying all at once. Regardless of if it's the immediate cause of death or just triggers another deadly event, I think this needs to be more well known that this method is not as harmless as it's often stated to be.

I know this is maybe more of an invert care post, but it's not like anyone is treating their tanks with hydrogen peroxide for anything besides algae outbreaks. Anyway, hopefully this will save a few shrimp.
 
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HomebroodExotics

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That really sucks to hear sorry for your loss. Just for my own knowledge what amount of hydrogen peroxide were you dosing and how often? Thanks
 

Subsea

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“I am also not 100% certain whether or not the lethality was from the peroxide *itself*, or possibly some kind of toxin released from a large number of dying dinoflagellates. Regardless of if it's the immediate cause of death or just triggers another deadly event, I think this needs to be more well known that this method is not as harmless as it's often stated to be.”

“I know this is maybe more of an invert care post, but it's not like anyone is treating their tanks with hydrogen peroxide for anything besides algae outbreaks. Anyway, hopefully this will save a few shrimp.”

@formallydehyde
It’s a Question of Balance. European reefers use low dose peroxide on sensitive shrimp tanks: Oxydator

I lost 99% of amphipod population when I dosed 1ml of 3% peroxide per 10G of tank water for 10 days.
 
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VintageReefer

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I’ve never heard of this and hydrogen peroxide has been used for over a decade

I’m not dismissing your results and outcome

To be clear, did you dose the tank, or dip a frag?

It could be some form of chain reaction from Dino’s or something else dying off rapidly
 

exnisstech

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How much did you use? I've used it many times but for gha not dinos so maybe that's the difference? I sprayed almost this entire rock and put it back in the tank of 30ish total gallons.
PXL_20240622_014712893.jpg
 

Subsea

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I’ve never heard of this and hydrogen peroxide has been used for over a decade

I’m not dismissing your results and outcome

To be clear, did you dose the tank, or dip a frag?

It could be some form of chain reaction from Dino’s or something else dying off rapidly.
OP dosed the tank.

“It could be some form of chain reaction from Dino’s or something else dying off rapidly“

Considering that snails die from eating certain cultivars of dinoflagellates, I would expect certain toxins to remain in dying Dino’s
 
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FoD

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I have also dosed peroxide with Fire shrimp and have never seen any issues. I have a much larger water volume. I am thinking you may have dosed way too much, or a spike from dino die off caused issues.
 
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formallydehyde

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“I am also not 100% certain whether or not the lethality was from the peroxide *itself*, or possibly some kind of toxin released from a large number of dying dinoflagellates. Regardless of if it's the immediate cause of death or just triggers another deadly event, I think this needs to be more well known that this method is not as harmless as it's often stated to be.”

“I know this is maybe more of an invert care post, but it's not like anyone is treating their tanks with hydrogen peroxide for anything besides algae outbreaks. Anyway, hopefully this will save a few shrimp.”

@formallydehyde
It’s a Question of Balance. European reefers use low dose peroxide on sensitive shrimp tanks: Oxydator

I lost 99% of amphipod population when I dosed 1ml of 3% peroxide per 10G of tank water.
If I search for "oxydator" and "shrimp" the all the top hits seem to be for freshwater shrimp tanks (usually when I see the term shrimp tank it means fresh water shrimp) and it seems to release the hydrogen peroxide slowly into a catalyst which breaks it down into oxygen. Maybe freshwater shrimp are more resilient or maybe barely any of the peroxide is actually released into the tank water.

That really sucks to hear sorry for your loss. Just for my own knowledge what amount of hydrogen peroxide were you dosing and how often? Thanks
Hard to say a super specific amount because I was spot treating the rock work, but I would have been using at most five milliliters of 3% peroxide in a syringe for spot treatment with the pumps off followed by immediate siphoning the area and doing 50-100% water changes over the course of a few hours. I was doing only doing this once a month or so, just once I couldn't get rid of enough of the dinos through siphoning alone, rather than being on a regular schedule.
 

HomebroodExotics

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If I search for "oxydator" and "shrimp" the all the top hits seem to be for freshwater shrimp tanks (usually when I see the term shrimp tank it means fresh water shrimp) and it seems to release the hydrogen peroxide slowly into a catalyst which breaks it down into oxygen. Maybe freshwater shrimp are more resilient or maybe barely any of the peroxide is actually released into the tank water.


Hard to say a super specific amount because I was spot treating the rock work, but I would have been using at most five milliliters of 3% peroxide in a syringe for spot treatment with the pumps off followed by immediate siphoning the area and doing 50-100% water changes over the course of a few hours. I was doing only doing this once a month or so, just once I couldn't get rid of enough of the dinos through siphoning alone, rather than being on a regular schedule.
Dino’s seem to be a lot more toxic than I used to think. When killing them and when they just exist in the aquarium it can be very detrimental for marine life. I wouldn’t necessarily blame the hydrogen peroxide but it’s very possible that it helps spread toxins around. Just my opinion and I’ll keep this in mind since I use hydrogen peroxide fairly often. Thanks for the info.
 

Subsea

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If I search for "oxydator" and "shrimp" the all the top hits seem to be for freshwater shrimp tanks (usually when I see the term shrimp tank it means fresh water shrimp) and it seems to release the hydrogen peroxide slowly into a catalyst which breaks it down into oxygen. Maybe freshwater shrimp are more resilient or maybe barely any of the peroxide is actually released into the tank water.


Hard to say a super specific amount because I was spot treating the rock work, but I would have been using at most five milliliters of 3% peroxide in a syringe for spot treatment with the pumps off followed by immediate siphoning the area and doing 50-100% water changes over the course of a few hours. I was doing only doing this once a month or so, just once I couldn't get rid of enough of the dinos through siphoning alone, rather than being on a regular schedule.
Your follow up of immediate siphoning up area would not have recovered much of the 5ml of peroxide used during spot treatment in tank. If this is a 20G tank, your concentration was more than double what I dosed. However I dosed for 10 days to eliminate GHA.
 
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formallydehyde

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@brandon429
Thoughts ? Experiences ?
In case he doesn't get around to this thread, I finally found a couple of the posts I was reading months ago after torturing Google and he was actually one of the people who stated it kills shrimp.
list of sensitives:

#1 lysmata shrimp are nearly guaranteed to die with any dose in-tank. fascinating metabolic weakness to peroxide
#2 anemones get offended, deflate, but I don't recall any dying
#3 xenia usually melts
#4 macro algae die for obvious reasons
#5 coralline algae is likely to bleach out, comes back about 80% of the time
#6 pods don't usually die at 1:10 doses until we exceed that to 3-4 mils per 10 gallons. if light pod death happened for someone at 1:10 dose I would not be surprised.

I don't have any fish we keep listed as sensitive to the 1:10 ratio though now that perx is used for fish disease control, Humblefish on his site has an exhaustive 200-fish count detailed list of max ld50 doses and sustain times.

pretty much all sps are tolerant for our 1:10 jobs and all lps.


***if peroxide is causing binding or liberation issues with iron, any other micronutrient, or any metals, we'd see it in that ten year list of tank applications as random tank deaths. that's not on file.
 

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In case he doesn't get around to this thread, I finally found a couple of the posts I was reading months ago after torturing Google and he was actually one of the people who stated it kills shrimp.
I noticed that amphipods were on the questionable kill list at 1ml/10G which is what I experienced with more than 95% reduction in population in the long haul. I suspect that I destroyed their food source of film algae.
 
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brandon429

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It's fascinating what patterns and predictions can be drawn from work threads, huge groups of reef tanks all running a given method

By page two of the first peroxide threads we tried, it was evident lysmata were dying at an alarming rate. And then not much else... very interesting tight range risks from something at the time welcomed by no reef chemists, Justin C always spoke of its use. His blog entry was the first I'd heard of it in reefing in 2009.


Peroxide went from something absolutely frowned upon, claimed unpredictable/ destructive oxidizer to add/ into a permanent reefing tool that's quite predictable. If we check the hobby in 2050, we will still be using peroxide routinely. That's the bet.
 

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I have never lost a shrimp after using hydrogen peroxide. My fire shrimp in particular was a rock star while I was using it to help control a disease outbreak. 3 years later and it is still alive.
 
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formallydehyde

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It's fascinating what patterns and predictions can be drawn from work threads, huge groups of reef tanks all running a given method

By page two of the first peroxide threads we tried, it was evident lysmata were dying at an alarming rate. And then not much else... very interesting tight range risks from something at the time welcomed by no reef chemists, Justin C always spoke of its use. His blog entry was the first I'd heard of it in reefing in 2009.
I also dismissed the first shrimp death as coincidental partly because of it not harming anything else. I even accidentally hit my tuxedo urchin with it pretty directly because he was somewhere I couldn't see. He dropped all his objects and ran, but was completely fine after. My snails, lettuce slug, crabs, corals, etc did not even seem to notice.

It's too bad that the risk to shrimp and a few other things got kind of lost in the telephone game after the initial threads.
 
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formallydehyde

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I have never lost a shrimp after using hydrogen peroxide. My fire shrimp in particular was a rock star while I was using it to help control a disease outbreak. 3 years later and it is still alive.
I am glad it worked for you and your shrimp was okay.

Regardless, I think for anyone doing peroxide treatment it would be a good idea to either remove the shrimp from the tank and put them in another tank for a couple days and do at least a 100% water change before returning them, or if spot treating for algae, only use it on rockwork you can pull outside the tank and rinse it thoroughly before returning it to the tank (which other people do successfully). Otherwise I think it's playing Russian Roulette with their lives.

Personally, in the future if I get another dinoflagellate outbreak I'll probably just invest in an inline UV sterilizer instead. Unfortunately that wasn't possible on my 20 gallon without a sump, but I can do that on my new larger system.
 

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peroxide works, no doubt. ...
being stupid with it is a disaster
I zapped a 210, lost all shrimp, clams and most sps with a unmonitored auto dosing with the 35% stuff. ...
I got a thread here on it, tanks looks post nuclear...
now I got a build thread ...

I’ll use it again if warranted, just with caution

yeah it really helps if you can either lift the rock out OR turn off flow and then very slowly push out the peroxide over the bubble algae (even better, if its the big “banana” type, use a needle and inject it)
… IME it isn’t all that deadly to corals but shrimp seem sensitive to it

not really, although shrimp can be sensitive…. generally speaking you can either spot treat with a turkey baster/hypo ( my preference) or use a dosing pump… many threads on both methods

..the cheap grocery store 3% stuff, squirt point blank on exposed rock if possible, replace, watch it fizzz
…watch out for shrimp
I agree
 

Dburr1014

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1ml of 3% per 10 gallons is the dose.
To say don't use it, it kills shrimp is false.

It should read, if you overdose your tank, shrimp will die.
Which is known that overdosing kills live stock.

5ml is a 50 gallon dose.

Sorry you lost your shrimp.
 

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