Beware of Vinegar - The Pump Killer

Haberdasher

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Been using muriatic acid for years. Great stuff. Vinegar is expensive for how much you get and how much you need to use to get the job done. One bottle of muriatic acid is cheap, you don't need very much to do the job, and it works faster.
 

Buku

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I have to agree, that the type of plastic could impact the rate that acetic acid penetrates. Maybe some pumps could be cleaned in vinegar and never have an issue. All I know is that Vortech's (and most likely Koralia's), appear to allow acetic acid to get through their plastic covering.

I honestly think it’s a vortech manufacturing defect. I’ve had to replace wetsides on 4 MP60s, 4 MP40s, and 3 MP10s. All of which I never used vinegar on. At most I would soak the cage and bottom. The magnet I was always able to just scrub off. The magnet blowouts is the reason I sold off my vortechs and went with tunzes. One of the 60 replacements rusted literally in months of getting a new wet side. Noticed it the first time I cleaned it.

I also agree with the muractic acid. I will fill up a 5 gallon bucket and dump 1/2-1C of acid in. A 5 minute dip and you can rinse/scrub everything off.

On a happier note to save you money, ecotech will warranty the wetsides even if it’s out of warranty. One of the 60s was years and years out of warranty. All they wanted from me was a picture of the Wetside and the serial on the back of the drive. Then asked how long it had been used in the tank.
 

Streetcred

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If this is indeed the case then any other pumps, say Tunze, should experience the same issue with the impellers. I have Tunze pumps, some 1+5 years old, always cleaned them in vinegar soaked for 2 weeks at a time. NEVER have experienced this problem.

I would be interested to know the chemical reaction that can cause metal swelling. ;-)
 

BiGGiePauls33

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This is the brand of citric acid I use.
Screenshot_20190830-231446.png
Screenshot_20190830-231446.png
 

12gallonsofhex

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I have posted bits and piece of my vinegar story over the past three years, and I thought it would be beneficial if one post contained all that I've learn. You'll be surprised! This story will contain three parts; my history with vinegar, the cause and simplified chemistry what's happening; and the solution to cleaning your pumps without fear of swelling magnets.


MY STORY

I've been using MP's for many years, and as a good boy, cleaned the wetsides in vinegar (aka, acetic acid) to make them look good and function correctly. I had a very simple way of doing this by immersing the entire wetside in straight vinegar over night and then rinsing and putting back into service.

Cleaning MP40 in Container.jpg



If anyone is interested, this small plastic container that perfectly fits an MP40 wetside is a one pint talenti ice cream (gelato) container....an overpriced ice cream my wife enjoys....too many times!
Talenti.jpg


About three and a half years ago I found one of my MP40 wetsides slowly spinning. To be crystal clear, the entire wetside...cage and all, was spinning. When I pulled it out I found the magnet had swelled and was binding to the body of the powerhead, causing the entire thing to spin.

1567041664548.png



I wasn't a happy camper, but over the next couple months, two more were found with swollen magnets (plastic case either swollen and/or cracked), and now also not functioning.

1567041726890.png


1567041764829.png



Now this isn't just an MP thing. In retrospect, I had four Koralia Evolution powerheads before switching over to MP's. All four were dead in the water within a year of purchasing new. Two with obvious swollen magnetic portions of the impeller shaft, and two that I couldn't even get the impellers out of the body of the powerhead because they were swollen and stuck within the body. Note that these powerheads were also regularly cleaned in vinegar.

So I have a confession...."Bless me Father for I have sinned"....my wife didn't know what I paid for all the MP's I have...and now I need to go out and drop another $225 for three wetsides. I wasn't happy!!! Note, if I die, my wife will be selling MP40's for about $20 - $25, half of what I supposedly paid.

To finish this story, I later had three MP10's do the same thing. My wife will be selling these for $15 - $20 a piece. Now I know, with six MP's with new wetsides, you're all waiting for me to die!


WHY IMPLICATE VINEGAR

So I was puzzled why my overpriced MP's crapped out, and about six months after loosing my first MP, I came across a post by @Randy Holmes-Farley in which he posted:

"I think the effect on plastic may be worse with vinegar than muriatic acid but it may depend on the plastic.

Vinegar can be in the form of acetic acid and that neutral molecule can enter plastic. Diluted muriatic acid won't have any neutral acidic molecules in it to enter plastic, so just exposes the outermost leading edge of plastic. So while the muriatic acid after dilution is a much stronger acid, i would not assume it is worse on plastics."



This made perfect sense! To clarify, charged molecules won't penetrate plastic, but neutral small molecules will. I will repeat that saying it differently....ionic molecules will react at the surface while small neutral molecules will potentially penetrate that material.

If we look at acids in aqueous solution, they dissociate into ions, which is commonly shown as:

HA(aq) + H2O(l) ⇌ H3O+(aq) + A−(aq)

where HA is the acid. Note that the left side is "neutral" while the right side of the reaction contains "charged" molecules (ions). Specifically, for acetic acid (vinegar), this dissocation looks like this:

CH3COOH + H20 ⇌ H3O+ + CH3COO-

Now here's the kicker....some acids dissociate easily and readily while others dissociate very poorly. In the case of acetic acid, it dissociates very poorly, with the majority still in the neutral CH3COOH configuration. To repeat what I said above, charged ions do not penetrate, while small neutral molecules can.

So what is happening when you clean your parts in vinegar, is that it being neutral, has the abililty to penetrate the plastic and, if within the plastic is metal, cause it to oxidize (rust), and swell. Now this doesn't happen over night, or by one cleaning, but happens over time....months, maybe years, but it will happen. In addition, the type of plastic could impact how quickly (or slowly) the acid penetrates.

Don't get me wrong, vinegar is still great for cleaning tanks and pure plastic parts, but I'd avoid it with metal parts encased in plastic (impellers and pumps.) If the cages alone need to be cleaned of coraline, I'd still consider cages only to be soaked in vinegar. But plastic encased magnets...NO, NO, NO!


IF I CAN'T USE VINEGAR, WHAT AM I TO DO

So what can you use to clean your powerheads and pumps that won't potentially cause the magnets to rust and swell and ruin your pumps? We need to find acids that dissociate completely and/or are too large to penetrate the plastic.

Well there just happens to be two readily available acids available that are reasonably price, and in my opinion, with one, clean better (faster) than vinegar. These two acids are Muriatic Acid and Citric Acid.

Muriatic acid (dilute hydrochloric acid) is available at HD and pool stores (and I'm sure other places as well.) One note with muriatic acid, it is hydrochloric acid and needs to be handled with care. It will burn you, cause for holes in your cloths, and is dangerous. So wear rubber gloves, eye protection and be careful.

For cleaning tank parts, I'd recommend dilution 1 to 10. Even at this dilution, it will clean pumps and whatever, much faster than vinegar. You'll actually see the calcification fizz off the equipment.

The other acid that is pump safe is citric acid. You can find five pounds on ebay for a reasonable amount of money....a life time supply. Here you want to dilute about 1 cup to a gallon of water. Throw your pumps into this solution and allow to sit over night and you should find a cleaned pump


CONCLUSION

Vinegar, being a neutral acid, will penetrate plastics. If metal is encased in this plastic, it will find it's way and cause that metal to rust and swell. To avoid this, use other acids, such as muriatic acid or citratic acid to clean your pumps...and have them last forever!
Thank you for sharing your experience and saving your fellow reefers some headaches! Good write up.
 

MartinWaite

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I was wondering if you could use an ultrasonic jewelry cleaner with just rodi?
Yes I'm sure you can as I use mine for cleaning alsorts but have never tried aquarium parts yet but I think I will next time I normally fine red hot water over the parts then soak in the red hot water then scrub them clean
 

Jeferson Stutz

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Been using vinegar to clear my WPs for a while, but always 10:1. Nothing more then an hour, After that I brush them with a smooth toothbrush.

Hope this helps,

Jeff
 

BiGGiePauls33

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I have posted bits and piece of my vinegar story over the past three years, and I thought it would be beneficial if one post contained all that I've learn. You'll be surprised! This story will contain three parts; my history with vinegar, the cause and simplified chemistry what's happening; and the solution to cleaning your pumps without fear of swelling magnets.


MY STORY

I've been using MP's for many years, and as a good boy, cleaned the wetsides in vinegar (aka, acetic acid) to make them look good and function correctly. I had a very simple way of doing this by immersing the entire wetside in straight vinegar over night and then rinsing and putting back into service.

Cleaning MP40 in Container.jpg



If anyone is interested, this small plastic container that perfectly fits an MP40 wetside is a one pint talenti ice cream (gelato) container....an overpriced ice cream my wife enjoys....too many times!
Talenti.jpg


About three and a half years ago I found one of my MP40 wetsides slowly spinning. To be crystal clear, the entire wetside...cage and all, was spinning. When I pulled it out I found the magnet had swelled and was binding to the body of the powerhead, causing the entire thing to spin.

1567041664548.png



I wasn't a happy camper, but over the next couple months, two more were found with swollen magnets (plastic case either swollen and/or cracked), and now also not functioning.

1567041726890.png


1567041764829.png



Now this isn't just an MP thing. In retrospect, I had four Koralia Evolution powerheads before switching over to MP's. All four were dead in the water within a year of purchasing new. Two with obvious swollen magnetic portions of the impeller shaft, and two that I couldn't even get the impellers out of the body of the powerhead because they were swollen and stuck within the body. Note that these powerheads were also regularly cleaned in vinegar.

So I have a confession...."Bless me Father for I have sinned"....my wife didn't know what I paid for all the MP's I have...and now I need to go out and drop another $225 for three wetsides. I wasn't happy!!! Note, if I die, my wife will be selling MP40's for about $20 - $25, half of what I supposedly paid.

To finish this story, I later had three MP10's do the same thing. My wife will be selling these for $15 - $20 a piece. Now I know, with six MP's with new wetsides, you're all waiting for me to die!


WHY IMPLICATE VINEGAR

So I was puzzled why my overpriced MP's crapped out, and about six months after loosing my first MP, I came across a post by @Randy Holmes-Farley in which he posted:

"I think the effect on plastic may be worse with vinegar than muriatic acid but it may depend on the plastic.

Vinegar can be in the form of acetic acid and that neutral molecule can enter plastic. Diluted muriatic acid won't have any neutral acidic molecules in it to enter plastic, so just exposes the outermost leading edge of plastic. So while the muriatic acid after dilution is a much stronger acid, i would not assume it is worse on plastics."



This made perfect sense! To clarify, charged molecules won't penetrate plastic, but neutral small molecules will. I will repeat that saying it differently....ionic molecules will react at the surface while small neutral molecules will potentially penetrate that material.

If we look at acids in aqueous solution, they dissociate into ions, which is commonly shown as:

HA(aq) + H2O(l) ⇌ H3O+(aq) + A−(aq)

where HA is the acid. Note that the left side is "neutral" while the right side of the reaction contains "charged" molecules (ions). Specifically, for acetic acid (vinegar), this dissocation looks like this:

CH3COOH + H20 ⇌ H3O+ + CH3COO-

Now here's the kicker....some acids dissociate easily and readily while others dissociate very poorly. In the case of acetic acid, it dissociates very poorly, with the majority still in the neutral CH3COOH configuration. To repeat what I said above, charged ions do not penetrate, while small neutral molecules can.

So what is happening when you clean your parts in vinegar, is that it being neutral, has the abililty to penetrate the plastic and, if within the plastic is metal, cause it to oxidize (rust), and swell. Now this doesn't happen over night, or by one cleaning, but happens over time....months, maybe years, but it will happen. In addition, the type of plastic could impact how quickly (or slowly) the acid penetrates.

Don't get me wrong, vinegar is still great for cleaning tanks and pure plastic parts, but I'd avoid it with metal parts encased in plastic (impellers and pumps.) If the cages alone need to be cleaned of coraline, I'd still consider cages only to be soaked in vinegar. But plastic encased magnets...NO, NO, NO!


IF I CAN'T USE VINEGAR, WHAT AM I TO DO

So what can you use to clean your powerheads and pumps that won't potentially cause the magnets to rust and swell and ruin your pumps? We need to find acids that dissociate completely and/or are too large to penetrate the plastic.

Well there just happens to be two readily available acids available that are reasonably price, and in my opinion, with one, clean better (faster) than vinegar. These two acids are Muriatic Acid and Citric Acid.

Muriatic acid (dilute hydrochloric acid) is available at HD and pool stores (and I'm sure other places as well.) One note with muriatic acid, it is hydrochloric acid and needs to be handled with care. It will burn you, cause for holes in your cloths, and is dangerous. So wear rubber gloves, eye protection and be careful.

For cleaning tank parts, I'd recommend dilution 1 to 10. Even at this dilution, it will clean pumps and whatever, much faster than vinegar. You'll actually see the calcification fizz off the equipment.

The other acid that is pump safe is citric acid. You can find five pounds on ebay for a reasonable amount of money....a life time supply. Here you want to dilute about 1 cup to a gallon of water. Throw your pumps into this solution and allow to sit over night and you should find a cleaned pump


CONCLUSION

Vinegar, being a neutral acid, will penetrate plastics. If metal is encased in this plastic, it will find it's way and cause that metal to rust and swell. To avoid this, use other acids, such as muriatic acid or citratic acid to clean your pumps...and have them last forever!
Thanks for posting the article.
 

CoralNerd

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Funny timing my wife just came home with a big bottle of vinegar she got on sale lol.
Thank you @redfishbluefish, for the heads up I'm going to switch to citratic acid as I love my mp40s. I wish Ecotech would read this thread.
 

Justins13

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I quit using vinegar to clean my Neptune WAVs out of my six WAVs all had been warranted once and a couple twice within the first 2 years. And it seemed all were shortly after soaking in vinegar.
 

Mike.P

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I have posted bits and piece of my vinegar story over the past three years, and I thought it would be beneficial if one post contained all that I've learn. You'll be surprised! This story will contain three parts; my history with vinegar, the cause and simplified chemistry what's happening; and the solution to cleaning your pumps without fear of swelling magnets.


MY STORY

I've been using MP's for many years, and as a good boy, cleaned the wetsides in vinegar (aka, acetic acid) to make them look good and function correctly. I had a very simple way of doing this by immersing the entire wetside in straight vinegar over night and then rinsing and putting back into service.

Cleaning MP40 in Container.jpg



If anyone is interested, this small plastic container that perfectly fits an MP40 wetside is a one pint talenti ice cream (gelato) container....an overpriced ice cream my wife enjoys....too many times!
Talenti.jpg


About three and a half years ago I found one of my MP40 wetsides slowly spinning. To be crystal clear, the entire wetside...cage and all, was spinning. When I pulled it out I found the magnet had swelled and was binding to the body of the powerhead, causing the entire thing to spin.

1567041664548.png



I wasn't a happy camper, but over the next couple months, two more were found with swollen magnets (plastic case either swollen and/or cracked), and now also not functioning.

1567041726890.png


1567041764829.png



Now this isn't just an MP thing. In retrospect, I had four Koralia Evolution powerheads before switching over to MP's. All four were dead in the water within a year of purchasing new. Two with obvious swollen magnetic portions of the impeller shaft, and two that I couldn't even get the impellers out of the body of the powerhead because they were swollen and stuck within the body. Note that these powerheads were also regularly cleaned in vinegar.

So I have a confession...."Bless me Father for I have sinned"....my wife didn't know what I paid for all the MP's I have...and now I need to go out and drop another $225 for three wetsides. I wasn't happy!!! Note, if I die, my wife will be selling MP40's for about $20 - $25, half of what I supposedly paid.

To finish this story, I later had three MP10's do the same thing. My wife will be selling these for $15 - $20 a piece. Now I know, with six MP's with new wetsides, you're all waiting for me to die!


WHY IMPLICATE VINEGAR

So I was puzzled why my overpriced MP's crapped out, and about six months after loosing my first MP, I came across a post by @Randy Holmes-Farley in which he posted:

"I think the effect on plastic may be worse with vinegar than muriatic acid but it may depend on the plastic.

Vinegar can be in the form of acetic acid and that neutral molecule can enter plastic. Diluted muriatic acid won't have any neutral acidic molecules in it to enter plastic, so just exposes the outermost leading edge of plastic. So while the muriatic acid after dilution is a much stronger acid, i would not assume it is worse on plastics."



This made perfect sense! To clarify, charged molecules won't penetrate plastic, but neutral small molecules will. I will repeat that saying it differently....ionic molecules will react at the surface while small neutral molecules will potentially penetrate that material.

If we look at acids in aqueous solution, they dissociate into ions, which is commonly shown as:

HA(aq) + H2O(l) ⇌ H3O+(aq) + A−(aq)

where HA is the acid. Note that the left side is "neutral" while the right side of the reaction contains "charged" molecules (ions). Specifically, for acetic acid (vinegar), this dissocation looks like this:

CH3COOH + H20 ⇌ H3O+ + CH3COO-

Now here's the kicker....some acids dissociate easily and readily while others dissociate very poorly. In the case of acetic acid, it dissociates very poorly, with the majority still in the neutral CH3COOH configuration. To repeat what I said above, charged ions do not penetrate, while small neutral molecules can.

So what is happening when you clean your parts in vinegar, is that it being neutral, has the abililty to penetrate the plastic and, if within the plastic is metal, cause it to oxidize (rust), and swell. Now this doesn't happen over night, or by one cleaning, but happens over time....months, maybe years, but it will happen. In addition, the type of plastic could impact how quickly (or slowly) the acid penetrates.

Don't get me wrong, vinegar is still great for cleaning tanks and pure plastic parts, but I'd avoid it with metal parts encased in plastic (impellers and pumps.) If the cages alone need to be cleaned of coraline, I'd still consider cages only to be soaked in vinegar. But plastic encased magnets...NO, NO, NO!


IF I CAN'T USE VINEGAR, WHAT AM I TO DO

So what can you use to clean your powerheads and pumps that won't potentially cause the magnets to rust and swell and ruin your pumps? We need to find acids that dissociate completely and/or are too large to penetrate the plastic.

Well there just happens to be two readily available acids available that are reasonably price, and in my opinion, with one, clean better (faster) than vinegar. These two acids are Muriatic Acid and Citric Acid.

Muriatic acid (dilute hydrochloric acid) is available at HD and pool stores (and I'm sure other places as well.) One note with muriatic acid, it is hydrochloric acid and needs to be handled with care. It will burn you, cause for holes in your cloths, and is dangerous. So wear rubber gloves, eye protection and be careful.

For cleaning tank parts, I'd recommend dilution 1 to 10. Even at this dilution, it will clean pumps and whatever, much faster than vinegar. You'll actually see the calcification fizz off the equipment.

The other acid that is pump safe is citric acid. You can find five pounds on ebay for a reasonable amount of money....a life time supply. Here you want to dilute about 1 cup to a gallon of water. Throw your pumps into this solution and allow to sit over night and you should find a cleaned pump


CONCLUSION

Vinegar, being a neutral acid, will penetrate plastics. If metal is encased in this plastic, it will find it's way and cause that metal to rust and swell. To avoid this, use other acids, such as muriatic acid or citratic acid to clean your pumps...and have them last forever!

Thank you for putting this together, it's a great write up! And if you die, which I hope you don't, I'm calling your wife. :p
 

mkwarner77

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I'd never leave anything in vinegar that long. Knowing its an acid,a mild one, and can have detrimental effects not only on plastic but also metal with long soak times. I soak for 15-20 min, scrub off crust, rinse then soak again 15 min scrub and rinse. Its more work but all my pumps are 3 yrs old and still going.
 
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